| To
illustrate the experimental results taken with the single-sinker
densimeter, the following figure shows the investigated
pρT surface of ethane as a typical example.
| 
|
Survey of
the pρT surface of ethane measured with
the single-sinker densimeter [137];
each circle corresponds to a measured point. The grey
area corresponds to the pρT surface which
had previously been measured with the two-sinker densimeter
(see pρT
measurements). |
In
the second figure, a a brief comparison of the measurements
with the single-sinker densimeter with experimental results
of other investigators is presented for three representative
isotherms. This figure illustrates the small uncertainty of
the measurements with the single-sinker densimeter. The zero
line in the three diagrams corresponds to values calculated
from a preliminary equation of state for ethane. The measurements
with the single-sinker densimeter are represented by full
circles (•) and their uncetainty of ≤0.02% to
≤0.03% is illustrated by the yellow areas. The two upper
diagrams show that the results taken with the single-sinker
densimeter of Claus et al. (2003) agree very well with the
reference measurements of Funke et al. (2002), taken with
the two-sinker densimeter in the overlapping region for temperatures
from 240 K to 340 K at pressures up to 12 MPa. The experimental
results of ten other studies show systematic deviations from
the accurate measurements with the single-sinker densimeter
of up to ±0.2% and more than that.
This
example illustrates the wide operating range and the high
accuracy of the single-sinker densimeter.
| 
|
| Percentage
deviations of experimental densities ρexp
of ethane from values ρcalc calculated
from a preliminary equation of state (zero line) of
ethane (Annotation: In the meantime the final equation
of state for ethane was published [147].)
•, measurements with the single-sinker densimeter
(Claus et al. [137]),
where the yellow area corresponds to the experimental
uncertainty. ♦, measurements with the two-sinker
densimeter (Funke et al. [134]).
(For more details see [137].) |
|