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Research » pρT-Messwerte » Example single-sinker densimeter
pix pix pρT Measurements with the Single-Sinker Densimeter Using Ethane as an Example

To illustrate the experimental results taken with the single-sinker densimeter, the following figure shows the investigated pρT surface of ethane as a typical example.

Survey of the pρT surface of ethane measured with the single-sinker densimeter [137]; each circle corresponds to a measured point. The grey area corresponds to the pρT surface which had previously been measured with the two-sinker densimeter (see pρT measurements).

In the second figure, a a brief comparison of the measurements with the single-sinker densimeter with experimental results of other investigators is presented for three representative isotherms. This figure illustrates the small uncertainty of the measurements with the single-sinker densimeter. The zero line in the three diagrams corresponds to values calculated from a preliminary equation of state for ethane. The measurements with the single-sinker densimeter are represented by full circles (•) and their uncetainty of ≤0.02% to ≤0.03% is illustrated by the yellow areas. The two upper diagrams show that the results taken with the single-sinker densimeter of Claus et al. (2003) agree very well with the reference measurements of Funke et al. (2002), taken with the two-sinker densimeter in the overlapping region for temperatures from 240 K to 340 K at pressures up to 12 MPa. The experimental results of ten other studies show systematic deviations from the accurate measurements with the single-sinker densimeter of up to ±0.2% and more than that.

This example illustrates the wide operating range and the high accuracy of the single-sinker densimeter.

Percentage deviations of experimental densities ρexp of ethane from values ρcalc calculated from a preliminary equation of state (zero line) of ethane (Annotation: In the meantime the final equation of state for ethane was published [147].) •, measurements with the single-sinker densimeter (Claus et al. [137]), where the yellow area corresponds to the experimental uncertainty. ♦, measurements with the two-sinker densimeter (Funke et al. [134]). (For more details see [137].)

 
 
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